Probing metal cluster and metal oxide cluster interactions with organo-sulfur and Organo-phosphorous molecules using mass spectrometry and anion PES

Probing metal cluster and metal oxide cluster interactions with organo-sulfur and organo- phosphorus molecules using mass spectrometry and anion photoelectron spectroscopy

Public Reporting burden for this collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comment regarding this burden estimates or any other aspect of this collection of information, including ...

Fast-atom bombardment tandem mass spectrometry studies of organo-alkali-metal ions of small peptides. Competitive interaction of sodium with basic amino acid substituents.

Interaction of Prolin, Leucine and methylurea with inorganic cluster [(PO4)M12O36].nH2O; (M = Mo, W)

Three new inorganic-organic hybrid materials based on heteropolyoxometalates, [L-C6H14NO2]3[(PO4)Mo12O36].3H2O (1), [L-C5H10NO2]3[(PO4)W12O36].H2O (2), and [C2H7N2O]3[(PO4)W12O36]. 4H2O (3), where C6H14NO2, C5H10NO2, and C2H7N2O are protonated L-leucine, L-proline, and methylurea, respectively, have been synthesized and structurally characterized by some physico-chemical methods. Elemental anal...

Organo-Zintl clusters soluble in conventional organic solvents: setting the stage for organo-Zintl cluster chemistry.

Organo-Zintl cluster ions were synthesized by reactions of alkynes with Ge94- clusters in ethylenediamine. The triple bonds are hydrogenated to double bonds during the process. The resulting dial-kenylated species [RHC=CHGe9CH=CHR]2- have lower charge, their alkali-metal cations can be exchanged for tetralkylammonium cations, and the resulting compounds are soluble in nonpolar solvents. This wa...

Adsorption and Neutralization Chemistry of Dimethyl Methyl Phosphonate (DMMP) as an Organo-Phosphorous Pollutant (OPP) on the Surface of Nano-Structured Co3O4 and MnCo2O4 Catalysts

In this work, the practicality of catalytic surfaces of nano-structured Co3O4 and MnCo2O4 for the adsorption and neutralization reactions of dimethyl methyl phosphonate (DMMP) as an toxic agricultural organo-phosphorous pesticide has been investigated. The Co3O4 and MnCo2O4 NPs have been successfully prepared by precipitation method using cobalt nitrate and manganese nitrate as the precursors a...